Journal of Semnan University of Medical Sciences
Image Credit:Koomesh
Outline
Replacement of lemon juice wastes instead of strong inorganic acids in production of silica from rice husk and efficiency of produced adsorbents in removal of cadmium from aqueous solutions
Authors
Abstract
Introduction: Production of adsorbent using agricultural wastes has important economic and environmental advantages. The aim of this study was Production of silica absolutely using agricultural wastes and determination of efficiency of produced adsorbents in removal of cadmium from aqueous solutions. Materials and Methods: In this experimental study, two different type of acidic pretreatment and then thermal treatment was used for silica production from rice husk. The efficiency of the produced adsorbents was studied in four pH states, four cadmium concentration values, five adsorbents dosages and six different contact times. Cadmium concentration was determined by atomic absorption spectrophotometry. Results: silica was produced in the two procedures and both produced silica had good morphological and physical characteristics. The maximum efficiency of cadmium removal at pH= 6, adsorbent dosage of 3 g/l, contact time of 120 min and initial cadmium concentration of 5 mg/l, for rice husk silica produced by strong inorganic acids and waste lemon juice were respectively %90.1, %60.8. The adsorption processes followed the Freundlich isotherm)generally R2 ≥0.99(. Conclusion: According to the results of this study, good rice husk silica can be produced using absolutely agricultural wastes (rice husk and lemon juice) and produced silica can be used as an effective and cheap adsorbent for removal of cadmium from aqueous solutions
Highlights
References
- 1.Sobhanardakani SM. Jamali, and M. Maanijou, Evaluation of As, Zn, Cr and Mn concentrations in groundwater resources of Razan plain and preparation of zoning map using GIS. 2014.
- 2.Gupta V, Nayak A. Cadmium removal and recovery from aqueous solutions by novel adsorbents prepared from orange peel and Fe 2 O 3 nanoparticles. Chem Engin J 2012; 180: 81-90.
- 3.Gupta VK, Ali I. Removal of lead and chromium from wastewater using bagasse fly asha sugar industry waste. J Colloid Interface Sci 2004; 271: 321-328.
- 4.Buragohain M1, Bhuyan B, Sarma HP. Seasonal variations of lead, arsenic, cadmium and aluminium contamination of groundwater in dhemaji district, assam, India. Environ Monit Assess 2010; 170: 345-351.
- 5.Smith AH1, Steinmaus CM. Health effects of arsenic and chromium in drinking water: recent human findings. Annu Rev Public Health 2009; 30: 107-122.
- 6.Hou D, He J, L C, Ren L, Fan Q, Wang J, Xie Z. Distribution characteristics and potential ecological risk assessment of heavy metals (Cu, Pb, Zn, Cd) in water and sediments from Lake Dalinouer, China. Ecotoxicol Environ Saf 2013; 93: 135-144.
- 7.Brahman KD, Kazi TG, Afridi HI, Naseem S, Arain SS, Ullah N. Evaluation of high levels of fluoride, arsenic species and other physicochemical parameters in underground water of two sub districts of Tharparkar, Pakistan: a multivariate study. Water Res 2013; 47: 1005-1020.
- 8.Samaci , Kartal S, Sacmaci M. Determination of Cr (III), Fe (III), Ni (II), Pb (II) and Zn (II) ions by FAAS in environmental samples after separation and preconcentration by solvent extraction using a triketone reagent. Fresenius Environ Bull 2012; 21: 1563-1570.
- 9.Rajai G, poorkhbaz A, Hsarymotla QS. Heavy metals health risk assessment of groundwater resources Aliabad katol plain. J North Khorasan Univ Med Sci 2012; 4: 155-162 (Persian).
- 10.Argos M1, Kalra T, Pierce BL, Chen Y, Parvez F, Islam T, et al. A prospective study of arsenic exposure from drinking water and incidence of skin lesions in Bangladesh. Am J Epidemiol 2011; 174: 185-194.
- 11.Alipour Torab S. Removal of cadmium from agricultural wastewater using sugarcan bagasse. Nashrieh Shimi Va Mohandesi Shimi Iran 2010; 29: 99-107. (Persian).
- 12.Heidari M, Sarani S. Effects of lead and cadmium on seed germination, seedling growth and antioxidant enzymes activities of mustard (Sinapis arvensis L.). ARPN J Agri Biol Sci 2011; 6: 44-47.
- 13.Benguella B, Benaissa H. Cadmium removal from aqueous solutions by chitin: kinetic and equilibrium studies. Water Res 2002; 36: 2463-2474.
- 14.Mohan D, Singh KP. Single-and multi-component adsorption of cadmium and zinc using activated carbon derived from bagassean agricultural waste. Water Res 2002; 36: 2304-2318.
- 15.An D, et al. A study on the consecutive preparation of silica powders and active carbon from rice husk ash. Biomass Bioenergy 2011; 35: 1227-1234.
- 16.Wang FY, Wang H, Ma JW. Adsorption of cadmium (II) ions from aqueous solution by a new low-cost adsorbentBamboo charcoal. J Hazard Mater 2010; 177: 300-306.
- 17.Iran National Institute of Standard. Standard Number 1053: Drinking water -Physical and chemical specifications,General requirements.5th.revision. 2010.
- 18.Kumar U, Bandyopadhyay M. Fixed bed column study for Cd (II) removal from wastewater using treated rice husk. J Hazard Mater 2006; 129: 253-259.
- 19.Rahmani A, et al. Adsorption of fluoride from water by Al3+ and Fe3+ pretreated natural Iranian zeolites. Int J Environ Res 2010; 4: 607-614. (Persian).
- 20.Bhattacharya A, Mandal S, Das S. Adsorption of Zn (II) from aqueous solution by using different adsorbents. Chem Eng J 2006; 123: 43-51.
- 21.Kaya A, ren AH. Adsorption of zinc from aqueous solutions to bentonite. J Hazard Mater 2005; 125: 183-189.
- 22.Ghaneian MT, et al. Application of biosorption process by pomegranate seed powder in the removal of hexavalent chromium fromaqueous environment. Koomesh 2014; 15: 206-211. (Persian).
- 23.Zhang H, Zhao X, Ding X, Lei H, Chen X, An D, Li Y, Wang Z. A study on the consecutive preparation of d-xylose and pure superfine silica from rice husk. Bioresour Technol 2010; 101: 1263-1267.
- 24.Balalai F, Jafarian M, Soloki M. Using rice husk as a cheap solution for wastewater treatment. J Water Environ 2000; 41: 441-453.
- 25.Jamwal R, Mantri S. Utilization of rice husk for derivation chemicals. Nandini Consultancy, Global Information Source for Chemical, Pharmaceutical and Allied Industries.
- 26.Mehrasbi M. Heavy metal removal from aqueous solution by adsorption on modified banana shell. Iran J Health Environ 2008; 1: 57-66.
- 27.Kulkarni SJ, Jayant PK. Analysis of packed bed adsorption column with low cost adsorbent for cadmium removal. Int J Ther Environ Engine 2015; 9: 17-24.
- 28.Guo H, Zhang S, Kou Z, Zhai S, Ma W, Yang Y. Removal of cadmium (II) from aqueous solutions by chemically modified maize straw. Carbohydr Polym 2015; 115: 177-185.
- 29.Alipour Torab S. Removal of cadmium from agricultural wastes sugarcane bagasse. J Chem Engine 2011; 29: 57-66.
- 30.Gueu S, et al. Kinetics and thermodynamics study of lead adsorption on to activated carbons from coconut and seed hull of the palm tree. Int J Environ Sci Technol 2007; 4: 11-17.
- 31.Mahvi A, Bina B, Saeedi A. Heavy metal removal from industrial effluents by natural fibers. J Water Waste 2002; 43: 2-6.
- 32.Shoukati PS, et al. Elimination of heavy metals from wastewater by reusing the waste: Case study (cadmium salts by used spent soils that used in vegetable oil industries). 2008.
- 33.Hoseinzadeh E, Rahmanie AR. Evaluation of cadmium removal efficiency from aqueous solution by activated carbon derived from scrap tire. Koomesh 2014; 15: 557-566. (Persian).
- 34.Boamah PO, Huang Y, Hua M, Zhang Q, Liu Y, Onumah J, et al. Removal of cadmium from aqueous solution using low molecular weight chitosan derivative. Carbohydr Polym 2015; 122: 255-264.##.
Copyright
© 2016, Author(s). This open-access article is available under the Creative Commons Attribution 4.0 (CC BY 4.0) International License (https://creativecommons.org/licenses/by/4.0/), which allows for unrestricted use, distribution, and reproduction in any medium, provided that the original work is properly cited.
Similar Articles
Cadmium removability from aqueous solutions using TiO2 nano photocatalytic compound and rice husk silica
Nassehinia H, Mahmoodi A, Mehdinia SM. Cadmium removability from aqueous solutions using TiO2 nano photocatalytic compound and rice husk silica. koomesh. 2016;18(3):e151122. doi:
Investigation of the capability of regenerated rice husk silica to remove hydrogen sulfide pollution
Mehdinia SM, BinariAbdollatif P, Taghipor H. Investigation of the capability of regenerated rice husk silica to remove hydrogen sulfide pollution. koomesh. 2012;14(1):e152552. doi:
Analysis of Carbonated Biosorbents Application in Heavy Metal Removal from Synthetic Wastewater
Taghavi L, Nasseh I, Barikbin B, Nasseh N. Analysis of Carbonated Biosorbents Application in Heavy Metal Removal from Synthetic Wastewater. Ann Mil Health Sci Res. 2016;14(2):e11360. doi:
Evaluation of Cadmium removal Efficiency from aqueous solution by Activated Carbon Derived from Scrap Tire
Hoseinzadeh E, Rahmanie A. Evaluation of Cadmium removal Efficiency from aqueous solution by Activated Carbon Derived from Scrap Tire. koomesh. 2014;15(4):e152892. doi:
Application of biosorption process by pomegranate seed powder in the removal of hexavalent chromium fromaqueous environment
Ghaneian MT, Jamshidi B, Amrollahi M, Dehvari M, Taghavi M. Application of biosorption process by pomegranate seed powder in the removal of hexavalent chromium fromaqueous environment. koomesh. 2014;15(2):e152635. doi:
- Scopus by DOI: 0
Last Update: 4 days ago
- Scopus by Title: 0
Last Update: 4 days ago
- Scopus by Title (Ref): 0
Last Update: 4 days ago
- CrossRef: 0
Last Update: 10 hours ago
- OpenAlex: 0
Last Update: 12 hours ago
- OpenCitations: 0
Last Update: 5 days ago